2.4 Diesel Engines
Rudolf Diesel first developed Diesel engines in the 19th century. He did so because he wanted to develop an engine that was more efficient than an Otto engine and that could use poorer quality fuel than gasoline. The Diesel engine also operates on a four-stroke cycle, but there are some important differences. Diesel engines have a high compression ratio (CR)- a small Diesel engine has a CR of 13:1, while a high-performance Otto engine has a CR of 10:1. Upon the compression stroke (stroke 2), there is a high increase in temperature and pressure. In the third stroke, fuel is injected and it ignites because of the high temperature and pressure of the compressed air. You can see an animation of this at How Stuff Works (Brain, Marshall. 'How Diesel Engines Work' 01 April 2000. HowStuffWorks.com). Diesel engines use fuel more efficiently; and under comparable conditions, a Diesel engine will always get better fuel efficiency than a gasoline Otto engine. Essentially, Diesel engines operate by knocking. The continuous knocking has two consequences: 1) a Diesel engine must be more sturdily built than a gasoline engine, so it is heavier and has a longer life - 300,000-350,000 miles before major engine service, and 2) fuel standards are "backward" from that of gasoline; we want fuel to knock.
Diesel fuel has a much higher boiling range than gasoline. The molecules are larger than gasoline, and the octane scale cannot be used as a guide. The scale that is used for diesel fuel is called the cetane number. The compound, cetane, or hexadecane, C16H34, is the standard where the cetane number is 100. For the cetane number 0 (the other end of the scale), the chemical compound used is methylnaphthalene, an aromatic compound that doesn't knock. Most diesel fuels will have cetane numbers of 40-55, with the value in Europe on the higher end and the value in the US at the lower end of that range. In a refinery, diesel fuels are processed in the same fashion as jet fuels, using hydrogenation reactions to remove sulfur and nitrogen and reacting aromatics to hydro aromatics and cycloalkanes. Dewaxing also must be done to improve viscosity and low-temperature problems, particularly in colder climates. Therefore, the primary processes that are typical in a petroleum refinery apply to diesel fuel as well as jet fuel. Except in airplanes, diesel engines dominate internal combustion engine applications. They are standard for large trucks; dominate railways in North America and other countries; are common in buses; and are adapted in small cars and trucks, particularly in Europe.
Similar to gasoline, prices that affect the quality of diesel include 1) the price of crude oil, 2) the supply/demand of diesel, 3) local, state, and federal taxes, and 4) the distribution of fuel (i.e., the cost of transporting fuel to various locations). Above is a schematic of how these contribute to the cost of diesel.