
SCOT Process
Figure 10.6 illustrates how the SCOT Process is integrated with the Claus Unit to convert COS, CS2 and any remaining SO2 by reacting with H2 in the catalytic reactor back to H2S to be recycled to the Claus Unit to close the loop. The hydrogenating catalysts used in SCOT contain nickel or tungsten on alumina support, and the reaction takes place at 480-570°. By coupling Claus and SCOT processes, more than 99% of sulfur entering the Claus unit can be recovered as elemental sulfur to be sold as a refinery product.

Figure 10.6. The Shell Claus Off-gas Treatment (SCOT) process.
Credit: Dr. Semih Eser © Penn State is licensed under CC BY-NC-SA 4.0