Fundamentals of Atmospheric Science

4.3 Other Trace Gases

Hundreds of different trace gases have been measured in the atmosphere and perhaps thousands more have yet to be measured. Many of these are volatile organic compounds (VOCs). Volatile means that the compound may exist in the liquid or solid phase but that it easily evaporates. Organic means that the compound contains carbon but is not carbon dioxide, carbon monoxide, or carbides and carbonates found in rocks. There are also other chemicals like the nitrogen oxides (e.g., nitric oxide (NO), nitrogen dioxide (NO2), nitric acid (HNO3)), sulfur compounds (e.g., sulfur dioxide (SO2), sulfuric acid (H2SO4)) and halogen compounds (e.g., natural methyl chloride (CH3Cl), human-made chlorofluorocarbons (CCl2F2)). If we pay attention, we can often smell and identify many of these chemicals, even at trace levels, although some, like methane, carbon monoxide (CO), and chlorofluorocarbons are odorless. We enjoy smelling the VOCs emitted by trees in a forest – aah, that fresh pine smell – but we hold our nose to escape the smells of a stagnant swamp.

In addition to these thousands of chemicals that are emitted into the atmosphere every day, there are also some very reactive compounds that are created by atmospheric chemistry and play the important role of cleaning the atmosphere of many gases. The most important reactive gases are ozone (O3) and hydroxyl (OH). We will focus the discussion of atmospheric chemistry on these two.

The Atmosphere’s Oxidizing Capacity

Earth’s atmosphere is an oxidizing environment. This term means what you think it would: gases that are emitted into the atmosphere react in a way that increases their oxygen content. Gases that contain oxygen tend to be “stickier” on surfaces and more water soluble, which means that they stick when they hit a surface or they can be readily taken up in clouds and rain drops and be deposited on Earth’s surface. We call gases hitting the surface and sticking “dry deposition” and gases being taken up in precipitation and rained out “wet deposition.”

Let’s consider a natural gas that is very important in our lives – methane (a.k.a., natural gas). More and more methane is being extracted from below Earth’s surface and used to run our electrical power plants, heat our homes, cook our food, and, increasingly, to run our transportation vehicles. Methane is a simple molecule – CH4 – in which each of carbon’s four bonds is made with a hydrogen atom. Energy comes from heating methane to high enough temperatures that cause it to react, giving off energy as more stable molecules are formed. In complete combustion, each methane molecule is converted into CO2 and two H2O. In the process, four oxygen atoms or two oxygen molecules are consumed.

This same process occurs in the atmosphere, but at much lower temperatures and at a much slower rate. In both cases, the first step in the methane oxidation sequence is the reaction with the hydroxyl radical (OH). In water, hydroxyl loses an electron and is ionized (OH-), but in the atmosphere, hydroxyl is not ionized. We call OH a free radical because it has an odd number of electrons (eight for oxygen and one for hydrogen). Any gas with an odd number of electrons is reactive because the electrons want to be paired up in molecules because that makes them more stable.

Where does OH come from?

Before we tackle this question, let’s first look at where ozone (O3) comes from. We will start with the stratosphere (a.k.a, good ozone because it blocks solar UV that harms humans, other animals, agriculture, and ecosystems) and then eventually we will consider tropospheric ozone (a.k.a., bad ozone, which is the ozone that hurts our health when we breathe it and that damages plants and their fruit).

Discussion Activity: Trace Gases

(20 points for on-line, 3 discussion point for in class)

For this week's discussion activity, I would like you to think about which trace gas is the most important and why. By trace gas I mean a gas with a mixing ratio of less than 20 ppm in the atmosphere. Defend your choice. Use information from this lesson as well as other sources (credit them, please!) to describe the qualities of this gas that make you think that it is the most important trace gas. Then read the choices of your classmates and respond to their choices and follow-up with further questions and/or analysis.

  1. You can access the Trace Gases Discussion Forum in Canvas.
  2. Post a response that answers the question above in a thoughtful manner that draws upon course material and outside sources.
  3. Keep the conversation going! Comment on at least one other person's post. Your comment should include follow-up questions and/or analysis.

This discussion will be worth 3 discussion points. I will use the following rubric to grade your participation:

Discussion Activity Grading Rubric
Evaluation Explanation Available Points
Not Completed Student did not complete the assignment by the due date. 0
Student completed the activity with adequate thoroughness. Posting answers the discussion question in a thoughtful manner, including some integration of course material. 1
Student completed the activity with additional attention to defending his/her position. Posting thoroughly answers the discussion question and is backed up by references to course content as well as outside sources. 2
Student completed a well-defended presentation of his/her position, and provided thoughtful analysis of at least one other student’s post. In addition to a well-crafted and defended post, the student has also engaged in thoughtful analysis/commentary on at least one other student’s post as well. 3