Carbon is unquestionably one of the most important elements on Earth. It is the principal building block for the organic compounds that make up life. Carbon's electron structure gives it a plus 4 charge, which means that it can readily form bonds with itself, leading to a great diversity in the chemical compounds that can be formed around carbon; hence the diversity and complexity of life. Carbon occurs in many other forms and places on Earth; it is a major constituent of limestones, occurring as calcium carbonate; it is dissolved in ocean water and fresh water; and it is present in the atmosphere as carbon dioxide, the second most voluminous greenhouse gas and the trigger for the bulk of current global climate change.
The flow of carbon throughout the biosphere, atmosphere, hydrosphere, and geosphere is one of the most complex, interesting, and important of the global cycles. More than any other global cycle, the carbon cycle challenges us to draw together information from biology, chemistry, oceanography and geology in order to understand how it works and what causes it to change. The major reservoirs for carbon and the processes that move carbon from reservoir to reservoir are shown in Figure 5.1 below. You do not need to understand this figure yet, but just appreciate that there are many reservoirs and a lot of exchanges. The carbon cycle is anything but simple! We will discuss these processes in more detail and then we will construct and experiment with various renditions of the carbon cycle, but first, we will explore some of the history of carbon cycle studies.
The global carbon cycle is currently the topic of great interest because of its importance in the global climate system and also because human activities are altering the carbon cycle to a significant degree. The potential effects of human activities on the carbon cycle, and the implications for climate change, were first noticed and studied by the Nobel Prize winning Swedish chemist, Svante Arrhenius, in 1896. He realized that CO2 in the atmosphere was an important greenhouse gas and that it was a by-product of burning fossil fuels (coal, gas, oil). He even calculated that a doubling of CO2 in the atmosphere would lead to a temperature rise of 4-5°C -- amazingly close to the current estimates obtained with global, 3-D climate models that run on supercomputers. This early recognition of human perturbations to the carbon cycle and the climatic implications did not raise many eyebrows at the time, but humans' "experiment" inputting massive amounts of CO2 to the atmosphere was just beginning then. We will be referring to this "experiment" throughout the module.